Претрага
409 items
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Orthorhombic Crystal Structure of Grossular Garnet (Suva Česma, Western Serbia): Evidence from the Rietveld Refinement
Pavle Tančić, Slađana Dušanić, Suzana Erić. "Orthorhombic Crystal Structure of Grossular Garnet (Suva Česma, Western Serbia): Evidence from the Rietveld Refinement" in Powders, MDPI AG (2023). https://doi.org/10.3390/powders2020023
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Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)
In this paper, grandite core with Grs64±1Adr36±1Sps2composition was crystallographically studied. This core represents zone A of the macroscopically visiblefive A–E zones of the optically anisotropic Grs58–64 Adr36–42Sps2 grandite. The applied procedure includes the detailed analysis of the powder diffraction patterns, and the Rietveld refinements of the crystal structures in a series of 18 space groups and two mixtures, which were followed by the comparative analysis of the R-values, site occupancy factors, and the bond lengths and angles. Synthesis of all ...Pavle Tančić, Aleksandar Kremenović, Predrag Vulić. "Structural dissymmetrization of optically anisotropic Grs64±1Adr36±1Sps2 grandite from Meka Presedla (Kopaonik Mt., Serbia)" in Powder Diffraction, Cambridge University Press (CUP) (2019). https://doi.org/10.1017/S0885715619000897
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Kristalografsko proučavanje strukturne desimetrizacije granata grosularsko-andraditske izomorfne serije
Pavle I. Tančić (2016-09-21)U ovoj Doktorskoj disertaciji proučavano je pet različitih zona makroskopski zonarnog grandita sa lokaliteta Meka Presedla (Kopaonik, Srbija). Pomoću hemijske i elektronske analize mikroprobe preračunati su relativno visoko homogeni sastavi zona, t.j.: Grs64±1Adr36±1Sps2 (A), Grs62±1Adr38±1Sps2 (B), Grs59±2Adr40±2Sps2 (C), Grs58±2Adr41±2Sps2 (D) i Grs58±1Adr41±1Sps2 (E). Glavne promene u sastavima izražene formulom: Ca2,93-2,97Mn0,05-0,06Mg0,00-0,01Al1,14-1,26Fe3+0,72-0,83Ti0,00-0,02Si2,97-3,02O12 ukazuju da je jedina značajnija varijacija ustanovljena samo kod Al-Fe3+ raspodela u oktaedarskom položaju. Ovakav hemijski sastav je potvrđen i sa matematičkim proračunima iz IC i Raman analiza. Urađena ...Macroscopically zoned grandite, chemical analysis, electron microprobe analysis, Raman, Rietveld, structure, dissymmetrization, space groupPavle I. Tančić. "Kristalografsko proučavanje strukturne desimetrizacije granata grosularsko-andraditske izomorfne serije" in Универзитет у Београду, Универзитет у Београду, Рударско-геолошки факултет (2016-09-21)
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A tool for identifying the criticality in the disordered systems with metastable dynamics
Svetislav Mijatović, Dragutin Jovković, Sanja Janićević, Stefan Graovac, Đorđe Spasojević. "A tool for identifying the criticality in the disordered systems with metastable dynamics" in Physica A: Statistical Mechanics and its Applications, Elsevier BV (2021). https://doi.org/10.1016/j.physa.2021.125883
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Disordered kalsilite KAlSiO4
Kremenović Aleksandar, Vulić Predrag (2014)Kremenović Aleksandar, Vulić Predrag. "Disordered kalsilite KAlSiO4" in Acta Crystallographica Section C 70 no. 3, Copenhagen:International Union of Crystallography by Munksgaard (2014): 256-259. https://doi.org/10.1107/S2053229614002423
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Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)
Jelena Pantić, Vladimir Urbanovich, Vesna Poharc-Logar, Bojan Jokić, Marija Stojmenović, Aleksandar Kremenović, Branko Matović (2014)Sphene (CaTiSiO5), a calcium titanosilicate ceramic has been prepared from a powder mixture of CaCO3, TiO2 and SiO2 using vibro-milling for homogenization and activation of precursors. During the highpressure and high-temperature synthesis (HPS) process at 4 GPa and 1,200 °C, sphene undergoes into phase transition, from room-temperature phase P21/a to high-temperature phase A2/a. Evidence of that structural phase transition is given in this paper using infrared, Raman spectroscopy and X-ray powder diffraction. Rietveld refinement was employed to get the ...Jelena Pantić, Vladimir Urbanovich, Vesna Poharc-Logar, Bojan Jokić, Marija Stojmenović, Aleksandar Kremenović, Branko Matović. "Synthesis and characterization of high-pressure and high-temperature sphene (CaTiSiO5)" in Physics and Chemistry of Minerals, Springer Science and Business Media LLC (2014). https://doi.org/10.1007/s00269-014-0693-x
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Spin activity correlations in driven disordered systems
Statistics, Probability and Uncertainty, Statistics and Probability, Statistical and Nonlinear PhysicsĐorđe Spasojević, Sonja Radić, Dragutin Jovković, Sanja Janićević. "Spin activity correlations in driven disordered systems" in Journal of Statistical Mechanics: Theory and Experiment, IOP Publishing (2022). https://doi.org/10.1088/1742-5468/ac72a2
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Crystal structures and microstructures of ordered and disordered kalsilites. Is kaliophilite a KAlSiO4 polymorph or kalsilite polytype?
Kremenović Aleksandar, Dimitrijević Radovan, Dondur Vera, Lazić P. Biljana, Vulić Predrag, Cvetković Vladica (2011)Kremenović Aleksandar, Dimitrijević Radovan, Dondur Vera, Lazić P. Biljana, Vulić Predrag, Cvetković Vladica. "Crystal structures and microstructures of ordered and disordered kalsilites. Is kaliophilite a KAlSiO4 polymorph or kalsilite polytype?" in Meeting of the Swiss Crystallographic Association/SGK/SSCr Newsletter 84, Bern, Švajcarska:Swiss Crystallographic Association (2011): 34-34
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Low-temperature phase transition and magnetic properties of K3YbSi2O7
Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović (2021)alkalni silikati elemenata retkih zemalja, fazni prelazi, magnetne karakteristike, razdvajanje kristalnog polja, silikati lantanica... temperatures of data collections. Crystal 1 Crystal 2 Polymorph T (K) 298 293, 283, . . . , 213 �-K3YbSi2O7 (space group P63/mmc) 295† 100 203, 193, . . . , 93 �0-K3YbSi2O7 (space group Cmcm) † Repeated data collection for crystal 2 after the low-temperature study. Table 2 Experimental details. ...
... s and temperatures of data collections. Crystal 1 Crystal 2 Polymorph T (K) 298 293, 283, ..., 213 B-K3YbSi,O, (space group P63/mmc) 295+ 100 203, 193, ...,93 B’-K;YbSi,O; (space group Cmcm) + Repeated data collection for crystal 2 after the low-temperature study. from the known hexagonal polymorph ...
... so far, which crystallize in the space groups P63/mcm and P63/mmc, respectively (Vidican et al., 2003; Latshaw et al., 2016c; Dabić et al., 2019). The crystal structure of �-K3YbSi2O7 has been known for quite some time. It crystallizes in hexagonal space group P63/mcm with the following unit-cell ...Predrag Dabić, Volker Kahlenberg, Biljana Krüger, Marko Rodić, Sabina Kovač, Jovan Blanuša, Zvonko Jagličić, Ljiljana Karanović, Václav Petříček, Aleksandar Kremenović. "Low-temperature phase transition and magnetic properties of K3YbSi2O7" in Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, International Union of Crystallography (IUCr) (2021). https://doi.org/10.1107/S2052520621006077
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Crystal structure of K3EuSi2O7
alkalni silikati elemenata retkih zemalja, kristalna struktura, sinteza metodom fluksa, rendgenska difrakcija na monokristalu... tripotassium europium disilicate, K3EuSi2O7, has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the space group P63/mcm. In the crystal structure of the title compound, one part of the Eu cations are in a slightly distorted octahedral coordination and the ...
... focused on the synthesis of new potassium-REE silicates, single crystals of K3EuSi2O7 were obtained. K3EuSi2O7 crystallizes in the hexagonal space group P63/mcm (No. 193) and is isostructural with K3NdSi2O7, 12 K3REESi2O7 (REE = Gd–Yb),13 K3YSi2O7, 6 K3SmSi2O7, 7 K3ErSi2O7. 15 The report- ed compound ...
... Bondar and co-authors11 stated the existence of this phase, however, they reported only unit cell parameters (a = 9.98(1), c = 14.44(2) Å), space group (P63/mcm), chemical composition and described the morphology of crystals. Myers16 outlined the successful synthesis of K3REESi2O7 (REE = Eu, ...Sabina Kovač, Predrag Dabić, Aleksandar Kremenović. "Crystal structure of K3EuSi2O7" in Journal of the Serbian Chemical Society, National Library of Serbia (2021). https://doi.org/10.2298/JSC210218026K
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Rietveld crystal structure refinement of a natural rhombohedral grossular-andradite garnet from Serbia
Pavle Tančić, Aleksandar Kremenović (2022)Four macroscopically visible B–E (rim) zones, within a large natural ferric grossular garnet of Grs58–64Adr36–42 Sps2 composition, are described by means of Rietveld refinements of the crystal structures in a series of six space groups, followed by com parative analysis of the R-values, site occupancy factors, and bond lengths and angles. The garnet crystallized in the rhombohedral R63c space group. Various polyhedral distortions and structural or derdis or dervariations between the zones studied are also described and discussed. The ...Pavle Tančić, Aleksandar Kremenović. "Rietveld crystal structure refinement of a natural rhombohedral grossular-andradite garnet from Serbia" in Geological Quarterly, Polish Geological Institute - National Research Institute (PGI-NRI) (2022). https://doi.org/10.7306/gq.1639
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Temperature induced evolution of nanostructured Ni0.9Zn0.1O
Kremenović Aleksandar, Antić Bratislav, Vučinić-Vasić Milica, Colomban Philippe, Jovalekić Čedomir, Bibić Nataša, Kahlenberg Volker, Leoni Matteo (2010)The crystal structure and microstructure of as-prepared and annealed Ni0.9Zn0.1O were refined at room temperature in both the Fm (3) over barm and R (3) over barm space groups. It is shown that below the Neel point (458 K), where magnetic ordering triggers the presence of a trigonal strain, the common usage of a higher-symmetry non-admissible space group for crystal structure and microstructure analysis via the Rietveld method may result in both an incorrect structure description and incorrect microstructure ...Kremenović Aleksandar, Antić Bratislav, Vučinić-Vasić Milica, Colomban Philippe, Jovalekić Čedomir, Bibić Nataša, Kahlenberg Volker, Leoni Matteo. "Temperature induced evolution of nanostructured Ni0.9Zn0.1O" in Journal of Applied Crystallography no. 43, Denmark: Blackwell Munksgaard (2010). https://doi.org/10.1107/S0021889810019163
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Sinteza i strukturna karakterizacija novih cezijumskih i kalijumskih silikata sa elementima retkih zemalja
Predrag Z. Dabić (2022)Predmet i ciljevi naučnog istraživanja ove doktorske disertacije su sinteza i strukturna karakterizacija novih cezijumskih i kalijumskih silikata sa elementima retkih zemalja. Istraživanja su izvedena u okviru sistema SiO2–REE2O3–XF, gde REE predstavlja trovalentni katjon elementa retkih zemalja (Sc, Y, Sm, Eu, Gd, Ho, Er, Tm, Yb, Lu), dok X predstavlja jednovalentni katjon alkalnih metala (K, Cs). Rad na disertaciji bio je fokusiran na sintezu monokristala, određivanje kristalnih struktura, kao i na kristalografsko i kristalohemijsko ispitivanje sintetisanih monokristala. Monokristali su sintetisani ...alkalni silikati elemenata retkih zemalja, kristalna struktura, sinteza metodom fluksa, rendgenska difrakcija na monokristalu, elementi retkih zemaljaPredrag Z. Dabić. Sinteza i strukturna karakterizacija novih cezijumskih i kalijumskih silikata sa elementima retkih zemalja, Beograd : P. Dabić, 2022
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FTIR Spectroscopic Study Of S-Metolachlor Sorption On Inorganic And Organically Modified Montmorillonite From Bogovina
... that carbonyl group participate in the binding process. Sorption of S-metolachlor on HDTMA-montmorillonites causes the redshift of the C = O absorption band. Shifting to lower wavenumbers and joining with the deformation vibration band of water indicates that the C = O group participated in ...
... llonite) are typical for smectites with a high Al content in the octahedron position. The intercalation of HDTMA+ cations into the interlayer space produces redshift of the IR bands that originate from the vibrations of the adsorbed water, as a consequence of the reduction of the hydrogen bond ...
... significantly with increasing concentration of HDTMA+ cation. All these changes are related to the decreasing of the water content in the interlayer space by increasing the content of HDTMA. The occurrence of the stretching CH2 vibrations is generally the main difference in the spectrum of HDTMA modified ...Lazar Kaluđerović, Zorica Tomić, Jelena Bogosavljević, Ljubomir Životić, Maja Milošević. "FTIR Spectroscopic Study Of S-Metolachlor Sorption On Inorganic And Organically Modified Montmorillonite From Bogovina" in 3rd International and 15th National Congress - Soils for Future under Global Challenges, Sokobanja, Serbia, Serbian Society of Soil Science (2021)
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FTIR spectroscopic study оf S-мetolachlor сorption оn inorganic and organically modified montmorillonite from Bogovina
... the ammonium group and the montmorillonite surface. FTIR spectroscopy of samples with S-metolachlor Three bands at 1674, 1462, and 1363 cm'"! in the spectrum of pure S-metolachlor were assigned to stretching vibrations of the carbonyl group (C=O), pheny1 group and anilidic group respectively ...
... that the carbonyl group participate in the binding process. Sorption of S- metolachlor on HDTMA-montmorillonites causes the redshift of the C=O absorption band. Shifting to lower wavenumbers and jJoining with the deformation vibration band of water indicates that the C=O group participated in the ...
... stretching ' vibrations v.(CHs) of methyl group which is not bonded to the N atom (Li et al., 2008; Madejova et al., 2009). Most intensive absorption bands at 2918 cm ! and 2850 cm"! originate from asymmetric and symmetric stretching vibrations of CH> group respectively (Tomić et al., 2015). The ...Lazar Kaluđerović, Zorica Tomić, Jelena Bogosavljević, Ljubomir Životić, Maja Milošević. "FTIR spectroscopic study оf S-мetolachlor сorption оn inorganic and organically modified montmorillonite from Bogovina" in Book of Proceedings / 3rd International and 15th National Congress Soils for Future Under Global Challenges, 21-24 September 2021 Sokobanja, Serbia , Belgrade : Serbian Society of Soil Science (2021)
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A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties
Single crystals of the new disodium tricopper(II) tetrakis(hydrogenarsenate(V)) tetrahydrate, Na2Cu3(AsO3OH)4·4H2O were grown under hydrothermal conditions. The compound was characterized by room-temperature single-crystal X-ray diffraction, SEM-EDS analysis, Raman spectroscopy and magnetic susceptibility measurements. Na2Cu3(AsO3OH)4·4H2O represents a new layered structure-type [space group P21/c, a = 8.7089(17), b = 9.7452(19), c = 9.3353(19) Å, β = 92.63(3)°, V = 791.4(3) Å3, Z = 4]. The layers are normal to [100] and are composed of the isolated Cu3O12 units interconnected by AsO3OH coordination ...Na2Cu3(AsO3OH)4•4H2O, хидротермална синтеза, кристална структура, хидрирани хидрокси-арсенати, магнетна својстваTamara Đorđević, Ljiljana Karanović, Zvonko Jagličić. "A new copper(II) arsenate, Na2Cu3(AsO3OH)4·4H2O containing discrete [Cu3O12]18− units: Synthesis, crystal structure and magnetic properties" in Journal of Solid State Chemistry, Elsevier BV (2018). https://doi.org/10.1016/j.jssc.2018.05.024
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A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra
Tamara Đorđević, Ljiljana Karanović (2010)A new monoclinic polymorph of Ba(AsO3OH) was synthesized under hydrothermal conditions. It represents a previously unknown structure type. Its crystal structure was determined from a racemic twin using single-crystal X-ray diffraction data collected at 120 and 293 K [space group P21, a=7.2149(14)/7.2370(2), b=7.7028(15)/7.7133(2), c=21.7385(43)/21.8079(5) Å, β=95.95(3)/96.073(1)1, V=1201.6(4)/1210.51(5) Å3, Z=12]. The crystal structure of P21-Ba(AsO3OH) has a layered character and is built up of four types of regularly alternating layers parallel to (0 0 1). Every AsO3OH tetrahedron is chelating to two Ba atoms and ...Ba(AsO3OH), хидротермална синтеза, структурна анализа монокристала, Раманска спектроскопија, инфрацрвена спектроскопија, водоничне везе, хидрогенарсенати земноалкалних металаTamara Đorđević, Ljiljana Karanović. "A new polymorph of Ba(AsO3OH): Synthesis, crystal structure and vibrational spectra" in Journal of Solid State Chemistry, Elsevier BV (2010). https://doi.org/10.1016/j.jssc.2010.09.027
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Polymorphism and photoluminescence properties of K3ErSi2O7
alkalni silikati elemenata retkih zemalja, silikati lantanoida, polimorfizam, fotoluminescencija, kristalna strukturaPredrag Dabić, Marko G. Nikolić, Sabina Kovač, Aleksandar Kremenović. "Polymorphism and photoluminescence properties of K3ErSi2O7" in Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography (IUCr) (2019). https://doi.org/10.1107/S2053229619011926
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An update on the mineral-like Sr-containing transition metal arsenates
Tamara Đorđević, Ljiljana Karanović (2021)We report on the crystal structures of three novel synthetic SrM-arsenates (M = Ni and Fe3+), isostructural or structurally related to the minerals from tsumcorite, carminite and brackebuschite groups. They were synthesised under mild hydrothermal conditions and further characterised using single-crystal X-ray diffraction (SXRD), scanning electron microscopy with energy dispersive spectroscopy (SEMEDS) and Raman spectroscopy. SXRD and SEM-EDS yielded formulae: (I) SrNi2(AsO4)2·2H2O, (II) Sr1.4Fe3+ 1.6(AsO4)2(OH)1.6 and (III) SrFe3+(AsO4)(AsO3OH). All three structures are built up of slightly distorted MO6 octahedra ...арсенати метала, кристална структура, дифракција рендгенских зрака на монокристалима, хидротермална синтеза, Раманова спектроскопија, релевантна једињења у животној средини, арсенeochemistry and PetrologyTamara Đorđević, Ljiljana Karanović. "An update on the mineral-like Sr-containing transition metal arsenates" in Mineralogical Magazine, Mineralogical Society (2021). https://doi.org/10.1180/mgm.2021.41
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Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+
In this study, a new cobalt arsenate belonging to the alluaudite supergroup compounds with the general formula of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H, )0.5(H2O,H3O)0.5]2x+ (denoted as CoAsAllu) was synthesized under hydrothermal conditions. Its crystal structure was determined by a room-temperature single-crystal X-ray diffraction analysis: space group C2/c, a = 11.6978(8), b = 12.5713(7), c = 6.7705(5) Å, b = 113.255(5)◦, V = 914.76(11) Å3, Z = 2 for As6H8Co6O25. It represents a new member of alluaudite-like protonated arsenates and the first alluaudite-like phase ...супергрупа алуаудита, арсенати прелазних метала, хидротермална синтеза, кристална структура, хидратисани хидрокси-арсенати, стехиометрија, магнетна својстваTamara Đorđević, Ljiljana Karanović, Marko Jagodič, Zvonko Jagličić. "Water in the Alluaudite Type-Compounds: Synthesis, Crystal Structure and Magnetic Properties of Co3(AsO4)0.5+x(HAsO4)2−x(H2AsO4)0.5+x[(H,□)0.5(H2O,H3O)0.5]2x+" in Minerals, MDPI AG (2021). https://doi.org/10.3390/min11121372